NSC-173702. Show More. Molybdenum hexacarbonyl CAS 13939-06-5 WIKI information includes physical and chemical properties, USES, security data, NMR spectroscopy, computational chemical data and more. However, it is often made ​​in this manner in the laboratory, because the required equipment is expensive, and the compound can be acquired inexpensively. Catalytic reactions of formate: Part 1. The dipole moment of the complex is 0 Debye. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. Use the product Attributes below to configure the comparison table. We can help. Subscribe to our news feed for new products, industry news and trends. If not breathing, give artificial respiration. NSC173702. In organic synthesis, its derivatives are employed as catalysts. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. TSCA: TSCA. ©2021 Ereztech LLC. Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions. Rinse mouth with water. : AC190390000; AC190390100; AC190390500; AC190392500 CAS-No 13939-06-5 Synonyms Hexacarbonylmolybdenum Recommended Use Laboratory chemicals. Molybdenum hexacarbonyl is widely used in electron beam-induced deposition technique - it is easily vaporized and decomposed by the electron beam providing a convenient source of molybdenum atoms. This colorless compound, like its chromium and molybdenum analogs, is noteworthy as a volatile, air-stable derivative of tungsten in its zero oxidation state. Glass ampules, bottles or, are available for packaging. Forms used for industrial purposes include molybdenum oxide, molybdenum trioxide, molybdenum hexacarbonyl and molybdenum sulfide. Molybdenum and Tungsten Imido Alkylidene N-Heterocyclic Carbene Catalysts Bearing Cationic Ligands for Use in Biphasic Olefin Metathesis. For example, the reaction of [Mo (CO ) 4 ( piperidine ) 2] and triphenyl phosphine in dichloromethane, the cis-substituted [Mo ( CO) 4 (PPh3) 2 ] complex. Formula: C6MoO6. Foods high in molybdenum include legumes, nuts, dairy products, cereal grains and leafy green vegetables. Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-Molybdenum carbonyl (Mo(CO)6) Molybdenum carbonyl (Mo2(CO)12) hexacarbonylmolybdenum(0) Mo (C O)6. The development of a method that uses molybdenum hexacarbonyl [Mo (CO) 6] as carbon monoxide (CO) surrogate for the palladium‐catalyzed reductive cyclization of nitroalkenes into indoles or thienopyrroles is reported. Industrially, molybdenum compounds (about 14% of world production of the element) are used in high-pressure and high-temperature applications as pigments and catalysts. Hexacarbonyl Suppliers USA. [3] Mo(CO) 6 is also a popular reagent in organometallic synthesis [4] because one or more CO ligands can be displaced by other donor ligands. References. Ereztech synthesizes and sells additional MO-compounds. Ereztech manufactures and sells this product in small and bulk volumes. Molybdenum hexacarbonyl is used in the technique of electron beam -induced deposition of a precursor. Use this link for bookmarking this species for future reference. If breathed in, move person into the fresh air. Show this safety data sheet to the doctor in attendance. CHEBI:30508. The compound is relatively stable in air. It behaves similarly to the analogous tungsten complex. Information on this page: Reaction thermochemistry data; Mass spectrum (electron ionization) References; Notes This colorless compound is chromium and tungsten as its analogs, a volatile, relatively air- stable complex of molybdenum in the oxidation state zero. | All trademarks are property of their respective owners. Molybdenum hexacarbonyl has an octahedral ( Oh). Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Chemical intermediate For research and industrial use only 1.3. Thin Solid Films 2000, 358, 90. Molybdenum carbonyl. To purchase Molybdenum hexacarbonyl contact us at sales@ereztech.com, FAQs on Custom Metal-Organic Precursors Used for ALD, Careers at Ereztech: Leader in Metal-Organics, Auditing Custom Metal-Organics Manufacturing & Production, Innovative Approach to Scaling Up Silicon Tetraiodide, Scaling Up Cobalt Octacarbonyl and Its Derivatives, Ereztech manufactures and sells this product in small and bulk volumes. Consult a physician. Company Identification: Acros Organics BVBA Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium Molybdenum hexacarbonyl is used in the technique of electron beam -induced deposition of a precursor. Laser Technol. For additional analytical information or details about purchasing Molybdenum hexacarbonyl contact us at, If you don’t see the needed lot of Molybdenum hexacarbonyl below please contact customer support at, Ereztech synthesizes and sells additional, To purchase Molybdenum hexacarbonyl contact us at. Molybänhexacarbonyl reacts with 2,2 '-bipyridine in a heteroleptic complex of Mo ( CO) 4 ( bipy). EINECS 237-713-3. The Kohlenstoffmonoxidliganden in molybdenum hexacarbonyl can be substituted by other ligands. The oxidation state 0 is possible with carbon monoxide as ligand, such as in molybdenum hexacarbonyl, Mo(CO) 6. Substance name : MOLYBDENUM HEXACARBONYL Product code : INMO030 Formula : C6MoO6 Synonyms : MOLYBDENUM CARBONYL; HEXACARBONYLMOLYBDENUM Chemical family : METAL COMPOUND 1.2. Do NOT induce vomiting. MOLYBDENUM CARBONYL View entire compound with free spectra: 3 FTIR, and 4 Raman. Investigation of optical nonlinearity of C60 doped acetylenedicarboxylic acid polymer. Molybdenum carbonyl (Mo(CO)6) (8CI) Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. The table shows element percentages for Mo(CO) 6 (molybdenum hexacarbonyl). The two piperidine ligands in this yellow compound are labile bound, so that other ligands can be introduced under mild conditions. Molybdenum hexacarbonyl (also called molybdenum carbonyl) is the chemical compound with the formula Mo(CO) 6.This colorless solid, like its chromium and tungsten analogues, is noteworthy as a volatile, air-stable derivative of a metal in its zero oxidation state. (Hexacarbonylmolybdenum). Molybdenum-based technical chemicals exploit the versatility of molybdenum chemistry in oxidation states. Consult a physician. DOI: 10.1016/0304-5102(93)85074-4. Molybdenum hexacarbonyl, due to its ability easily vaporized and decomposed by the electron beam, is widely used in electron beam-induced deposition technique. It is used as a reagent in organometallic synthesis because of the displacement of carbonyl ligands by other donor ligands. Template: Infobox chemical / molecular formula search is not possible. Molybdenum hexacarbonyl. Journal of Molecular Catalysis 1993, 80 (2) , 151-163. Bis(t-butylimido)bis(dimethylamino)molybdenum, Dicarbonyl(pentamethylcyclopentadienyl)molybdenum dimer, P260-P262-P280-P301 + P310 + P330-P302 + P352 + P310-P304 + P340 + P310-P403 + P233, METAL CARBONYLS, SOLID, N.O.S. Molybdenum is an essential mineral in the body, just like iron and magnesium. Packaging 10, 50, 250 g in glass bottle Information on this page: Notes; Other data available: Gas phase thermochemistry data Move out of the dangerous area. [5] Details of the supplier of the safety data sheet Emergency Telephone Number Molybdenum hexacarbonyl, due to its ability easily vaporized and decomposed by the electron beam, is widely used in electron beam-induced deposition technique. It is a stable 18- Valenzelektronenkomplex. Element % C: 27.30: Mo: 36.34: O: 36.36: Isotope pattern for Mo(CO) 6. Many metal carbonyls are similar photochemically activated. Used in the grafting of silica, as a catalyst for epoxidation of olefins, in the adsorption of organosulfur compounds from liquid fuels, as a precursor for the manufacture of organomolybdenum dyes and for Molybdenum plating by thermal decomposition. Molybdenum disulphide (MoS 2) is employed as a heat-resistant lubricant or a lubricant additive. Wash off with soap and plenty of water. Dicyclopentadiene has an irritating odour and should be considered as toxic. Use this link for bookmarking this species for future reference. Molybdenum hexacarbonyl and related derivatives can be used as a catalyst in organic synthesis, for example, for alkyne metathesis and Pauson -Khand reaction. NSC 173702. DTXSID70894074. Consult a physician. 2015, 68, 60-66. (Select up to %1% total) Brand Reaction Suitability Assay. Molybdenum hexacarbonyl and related derivatives can be used as a catalyst in organic synthesis, for example, for alkyne metathesis and Pauson -Khand reaction. Product Name Molybdenum hexacarbonyl Cat No. We've been creating custom solutions since 1991. It is increasingly used for molybdenum plating by thermal decomposition. Have a unique need? [7] Safety and handling. The wavenumber of the CO stretching vibration of the free νCO carbon monoxide is at 2004 cm -1. For additional analytical information or details about purchasing Molybdenum hexacarbonyl contact us at sales@ereztech.com, If you don’t see the needed lot of Molybdenum hexacarbonyl below please contact customer support at sales@ereztech.com, Lot# 5/R/1/0618 Lot# 5/R/1/Mo50/419 Lot# 5R01620 Lot# 5R1920. Zidan, M. D.; Allaf, A. W.; Allahham, A.; Zier, A. Use this link for bookmarking this species for future reference. Photocatalytic hydrogen production from formate with chromium hexacarbonyl. The Mo-C distance is 206 pm. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. Product # Description 199958: Molybdenumhexacarbonyl, 98%, 577766: Molybdenumhexacarbonyl, ≥99.9% trace metals … Synonym: Hexacarbonylmolybdenum, Molybdenumhexacarbonyl, Molybdenum carbonyl, CAS Number 13939-06-5 | MDL Number MFCD00003466 | EC Number 237-713-3. Molybdenum hexacarbonyl was detected in trace concentrations in the gaseous exhalations of sewage sludge. The six Kohlenstoffmonoxidliganden are positioned radially around the central molybdenum atom. Molybdenum hexacarbonyl agent detailed information in Haz-Map database. Molybdenum hexacarbonyl weighs 1.96 gram per cubic centimeter or 1 960 kilogram per cubic meter, i.e. This product also utilized as a precursor for the manufacture of organomolybdenum dyes and for Molybdenum plating by thermal decomposition. We're here to answer any questions you have. A. Good yields of the corresponding products have been obtained with wide functional group tolerance and excellent regioselectivity. 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Dyes and for molybdenum plating by thermal decomposition total ) Brand reaction Suitability Assay with... % C: 27.30: Mo: 36.34: O: 36.36 Isotope... 2 ), 151-163 Kohlenstoffmonoxidliganden in molybdenum include legumes, nuts, dairy,. Metal carbonyls is molybdenum hexacarbonyl product code: INMO030 Formula: C6MoO6 Synonyms: carbonyl! The technique of electron beam, is widely used in the body, just like iron and magnesium donor.. Also utilized as a source of Mo ( CO ) 6 acceptor by reductive Hochdruckcarbonylierung of molybdenum atoms with under...
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